I looked at the logs for the RS IP camera a few minutes ago. The motion setup had triggered events and email sends.
I changed the settings to pointing to the Homeseer server (running STunnel) as you have above in the snapshots using SMTP port 25 and the emails went through.
07/09/2011 20:42:18 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:38:48 SMTP: Failed to send E-mail to "homeseer@gmail.com".
07/09/2011 20:38:44 Alert: Detected motion.
07/09/2011 20:36:10 SMTP: Failed to send E-mail to "homeseer@gmail.com".
07/09/2011 20:36:06 Alert: Detected motion.
07/09/2011 20:33:07 SMTP: Failed to send E-mail to "homeseer@gmail.com".
07/09/2011 20:33:03 Alert: Detected motion.
07/09/2011 20:38:44 Alert: Detected motion.
07/09/2011 20:36:10 SMTP: Failed to send E-mail to "homeseer@gmail.com".
07/09/2011 20:36:06 Alert: Detected motion.
07/09/2011 20:33:07 SMTP: Failed to send E-mail to "homeseer@gmail.com".
07/09/2011 20:33:03 Alert: Detected motion.
07/09/2011 20:42:18 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:46:45 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:46:38 Alert: Detected motion.
07/09/2011 20:44:44 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:44:37 Alert: Detected motion.
07/09/2011 20:42:18 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:46:38 Alert: Detected motion.
07/09/2011 20:44:44 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
07/09/2011 20:44:37 Alert: Detected motion.
07/09/2011 20:42:18 SMTP: Send E-mail OK by SMTP server [host: HomeseerIP].
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